|
|
3-benzyl-3,6_-dithio-6-(hydroxymethyl)-diketopiperazine + O2 <=> 3-benzyl-3,6_-disulfide-6-(hydroxymethyl)-diketopiperazine + H2O2
|
1.8.3.2
thiol oxidase
|
–
|
|
MetaCyc:
RXN-15684
|
|
|
|
S-adenosyl-L-methionine + N-desmethyl-gliotoxin <=> gliotoxin + S-adenosyl-L-homocysteine + H+
|
2.1.1
|
–
|
|
MetaCyc:
RXN-15686
|
|
|
|
3-benzyl-3,6-dihydroxy-6-(hydroxymethyl)-diketopiperazine + glutathione <=> 3-benzyl-3,6_-bis(glutathione)-_6-(hydroxymethyl)-diketopiperazine + H2O
|
2.5.1.18
glutathione transferase
|
–
|
|
MetaCyc:
RXN-15680
|
|
|
|
3-benzyl-3,6_-bis(cysteinyl)-_6-(hydroxymethyl)-diketopiperazine + H2O <=> 3-benzyl-3,6_-dithio-6-(hydroxymethyl)-diketopiperazine + NH3 + pyruvate
|
4.4.1
|
–
|
|
MetaCyc:
RXN-15683
|
|
|
|
cyclo(L-phenylalanyl-L-seryl) + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 3-benzyl-3,6-dihydroxy-6-(hydroxymethyl)-diketopiperazine + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
|
MetaCyc:
RXN-15679
|
|
|
|
L-phenylalanine + L-serine + ATP <=> cyclo(L-phenylalanyl-L-seryl) + ADP + phosphate + H+
|
6.3.2
|
–
|
|
MetaCyc:
RXN-15678
|
|
|
|
3-benzyl-3,6_-bis(cysteinylglycine)-_6-(hydroxymethyl)-diketopiperazine + H2O <=> 3-benzyl-3,6_-bis(cysteinyl)-_6-(hydroxymethyl)-diketopiperazine + glycine
|
3.4.13.19
membrane dipeptidase
|
–
|
|
MetaCyc:
RXN-15682
|
|
|
|
3-benzyl-3,6_-disulfide-6-(hydroxymethyl)-diketopiperazine <=> N-desmethyl-gliotoxin
|
not assigned
|
–
|
|
MetaCyc:
RXN-15685
|
|
|
|
3-benzyl-3,6_-bis(glutathione)-_6-(hydroxymethyl)-diketopiperazine <=> 3-benzyl-3,6_-bis(cysteinylglycine)-_6-(hydroxymethyl)-diketopiperazine + 5-oxoproline
|
4.3.2
|
–
|
|
MetaCyc:
RXN-15681
|
|